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Electro-oxidative C–H alkylation of quinoxalin-2(1H)-ones with organoboron compounds

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Radical cleavage of C–B bonds to accomplish C–H functionalization is synthetically appealing but practically challenging. We report herein a mild electro-oxidative method for efficient C–H alkylation of quinoxalin-2(1H)-ones by means… Click to show full abstract

Radical cleavage of C–B bonds to accomplish C–H functionalization is synthetically appealing but practically challenging. We report herein a mild electro-oxidative method for efficient C–H alkylation of quinoxalin-2(1H)-ones by means of radical addition reactions of alkyl boronic acids and esters and alkyl trifluoroborates to afford C–C coupled products.

Keywords: quinoxalin ones; oxidative alkylation; alkylation quinoxalin; electro oxidative

Journal Title: Green Chemistry
Year Published: 2021

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