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A transition metal-free α,β-dehydrogenation of ketones and aldehydes was developed. This reaction was conducted in a facile I2/KI/DMSO system to produce the corresponding unsaturated compounds in good to high yields.… Click to show full abstract
A transition metal-free α,β-dehydrogenation of ketones and aldehydes was developed. This reaction was conducted in a facile I2/KI/DMSO system to produce the corresponding unsaturated compounds in good to high yields. The gram-scale experiment also indicated the potential synthetic value of this new reaction in organic synthesis. In the reaction, DMSO acted as both solvent and mild oxidant.
Keywords:
iodine catalyzed;
ketones aldehydes;
dehydrogenation ketones;
aldehydes generating;
catalyzed dehydrogenation
Journal Title: New Journal of Chemistry
Year Published: 2020
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Journal Title: New Journal of Chemistry
Year Published: 2020
Link to full text (if available)
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recommendations!