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A novel μ-nitrido-bridged iron phthalocyanine dimer with eight peripheral 12-crown-4 units as an electron-donating substituent was synthesized and characterized. Examination of its methane oxidation activity in the presence of H2O2… Click to show full abstract
A novel μ-nitrido-bridged iron phthalocyanine dimer with eight peripheral 12-crown-4 units as an electron-donating substituent was synthesized and characterized. Examination of its methane oxidation activity in the presence of H2O2 in an acidic aqueous solution suggested that the high-valent iron oxo species generated in situ was unstable and the transiently generated decomposed species showed methane oxidation activity via Fenton-type reaction.
Keywords:
iron;
methane oxidation;
nitrido bridged;
oxidation activity
Journal Title: New Journal of Chemistry
Year Published: 2020
Link to full text (if available)
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Journal Title: New Journal of Chemistry
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!