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Metal-free photocatalytic hydrosilylation of olefins in the presence of photoinitiators

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A convenient metal-free photocatalytic hydrosilylation of a variety of linear and cyclic alkenes has been investigated. It was found that the free radical type photoinitiator Irgacure 2959 had a better… Click to show full abstract

A convenient metal-free photocatalytic hydrosilylation of a variety of linear and cyclic alkenes has been investigated. It was found that the free radical type photoinitiator Irgacure 2959 had a better effect on the hydrosilylation reaction; using 3 mol% photoinitiator Irgacure 2959, higher conversion rates can be obtained in the hydrosilylation of both some internal and terminal olefins. A new green method for hydrosilylation processes is achieved.

Keywords: hydrosilylation; free photocatalytic; hydrosilylation olefins; olefins presence; metal free; photocatalytic hydrosilylation

Journal Title: New Journal of Chemistry
Year Published: 2021

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