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The emergence of red fluorescence from two-dimensional nitrogenated-stanene oxide nanosheets.

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The instigation of fluorescence in 2D metal oxide nanosheets is a daunting task to achieve. In the present work, we have synthesized bright red fluorescent stanene oxide (rStNS nanosheets) using… Click to show full abstract

The instigation of fluorescence in 2D metal oxide nanosheets is a daunting task to achieve. In the present work, we have synthesized bright red fluorescent stanene oxide (rStNS nanosheets) using an exceptionally simple method. Tin(ii) chloride added to a complex solvent (non-aqueous solution) of acetone and acetonitrile was sonicated and incubated at ambient temperature for ∼six days. After three days (72 h), the solution turned light yellow with bright red fluorescence; this is possible due to interactions between Sn and nitrogen atoms in a nanoscale environment. The emission from rStNS nanosheets (λex = 370 nm) covered a broad range of the optical spectrum (with a prominent peak at 590 nm). Interestingly, after day five, the colour of the solution became darker, and the colour of fluorescence changed from red to green (gStNS nanosheets).

Keywords: red fluorescence; oxide nanosheets; fluorescence; emergence red; stanene oxide; fluorescence two

Journal Title: Nanoscale
Year Published: 2020

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