A novel metal-catalyzed cascade reaction of a stable low-molecular-weight vinyl azide surrogate bearing a β-oxygen substituent in a general fashion was disclosed. The orderly insertion of S-/O-nucleophiles and alkynes, for… Click to show full abstract
A novel metal-catalyzed cascade reaction of a stable low-molecular-weight vinyl azide surrogate bearing a β-oxygen substituent in a general fashion was disclosed. The orderly insertion of S-/O-nucleophiles and alkynes, for the first time, successfully afforded a diverse range of sulfuryl-substituted N-vinyl-1,2,3-triazoles in good yields.
               
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