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Cp*Ir(iii)- and Cp*Rh(iii)-catalyzed C(sp2)–H amination of arenes using thioethers as directing groups

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A mild and selective Cp*Ir(iii)- and Cp*Rh(iii)-catalyzed direct C(sp2)–H amination of arenes and three types of nitrene precursor reagents is reported, with the assistance of a thioether directing group. Click to show full abstract

A mild and selective Cp*Ir(iii)- and Cp*Rh(iii)-catalyzed direct C(sp2)–H amination of arenes and three types of nitrene precursor reagents is reported, with the assistance of a thioether directing group.

Keywords: iii iii; sp2 amination; catalyzed sp2; iii catalyzed; amination arenes

Journal Title: Organic chemistry frontiers
Year Published: 2021

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