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The first triphenylphosphine/sodium iodide driven photocatalytic decarboxylative cascade cyclization of 2-isocyano-biaryls with alkyl N-hydroxyphthalimide (NHP) esters was developed. This operationally simple protocol results in multiple carbon–carbon bond formation under transition… Click to show full abstract
The first triphenylphosphine/sodium iodide driven photocatalytic decarboxylative cascade cyclization of 2-isocyano-biaryls with alkyl N-hydroxyphthalimide (NHP) esters was developed. This operationally simple protocol results in multiple carbon–carbon bond formation under transition metal free conditions, affording a novel and environmentally benign entry to producing 6-alkyl phenanthridines with moderate to good yields.
Keywords:
nai driven;
photocatalytic decarboxylative;
driven photocatalytic;
pph3 nai;
cascade;
decarboxylative radical
Journal Title: RSC Advances
Year Published: 2020
Link to full text (if available)
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Journal Title: RSC Advances
Year Published: 2020
Link to full text (if available)
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recommendations!