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A dual-sensitized luminescent europium(iii) complex as a photoluminescent probe for selectively detecting Fe3+

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A new luminescent EuIII complex, namely [Eu2(BTFA)4(OMe)2(dpq)2] (1), in which BTFA = 3-benzoyl-1,1,1-trifluoroacetone and dpq = dipyrido [3,2-d:2′,3′-f] quinoxaline, has been designed and synthesized by employing two different ligands as… Click to show full abstract

A new luminescent EuIII complex, namely [Eu2(BTFA)4(OMe)2(dpq)2] (1), in which BTFA = 3-benzoyl-1,1,1-trifluoroacetone and dpq = dipyrido [3,2-d:2′,3′-f] quinoxaline, has been designed and synthesized by employing two different ligands as sensitizers. Crystal structure analysis reveals that complex 1 is composed of dinuclear EuIII units crystallized in the monoclinic P space group. Notably, 1 exhibits high thermal stability up to 270 °C and excellent water stability. The photoluminescence property of the complex is investigated. Further studies show 1 can recognize Fe3+ ions with high selectivity from mixed metal ions in aqueous solution through the luminescence quenching phenomenon. Furthermore, the recyclability and stability of 1 after sensing experiments are observed to be adequate. By virtue of the superior stability, detection efficiency, applicability and reusability, the as-prepared EuIII complex can be a promising fluorescent material for practical sensing.

Keywords: europium iii; luminescent europium; sensitized luminescent; iii complex; stability; dual sensitized

Journal Title: RSC Advances
Year Published: 2020

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