LAUSR

Quantum dots (QDs) solids with iodide passivation are a key component for most of the well-performing PbS QDs solar cells. Usually, iodide passivation of oleic acid (OA) capped PbS QDs films is achieved by a solid-state ligand exchange process using tetrabutylammonium iodide (TBAI). This ligand exchange process has generally been reported to be incomplete, especially in higher thicknesses, affecting the properties of the films adversely, producing inconsistent results in the device structures fabricated. The present study is based on a systematic investigation of the TBAI exchange on PbS QDs films and the performance of the resulting solar cells. We could achieve a complete TBAI exchange in a sufficiently thick (∼240 nm) and dense QDs film deposited by a minimum number of coating steps, through the optimization of the number of post-synthesis washing cycles on the QDs. Detailed studies were carried out investigating the effect of the number of washing cycles on the quantity of OA before and after the exchange, the ligand exchange efficiency, the development of trap states and the resulting photovoltaic device performance. A power conversion efficiency of 5.55% was obtained for a device subjected to an optimum number of washing cycles.