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Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex

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The facile synthesis of tetrahydroquinoline-based chiral carbene precursors is reported. A rare Au⋯H–C(sp3) interaction between Au(i) and the hydrogen atom was observed in the crystal structure of a related NHC–gold… Click to show full abstract

The facile synthesis of tetrahydroquinoline-based chiral carbene precursors is reported. A rare Au⋯H–C(sp3) interaction between Au(i) and the hydrogen atom was observed in the crystal structure of a related NHC–gold complex.

Keywords: chiral carbene; tetrahydroquinoline based; syntheses tetrahydroquinoline; based chiral; carbene precursors

Journal Title: RSC Advances
Year Published: 2020

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