"Bifunctional thiosquaramide catalyzed asymmetric reduction of dihydro-β-carbolines and enantioselective synthesis of (−)-coerulescine and (−)-horsfiline by oxidative rearrangement"

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Bifunctional thiosquaramide catalyzed asymmetric reduction of dihydro-β-carbolines and enantioselective synthesis of (−)-coerulescine and (−)-horsfiline by oxidative rearrangement

A simple and efficient asymmetric synthesis of THBCs through a chiral thiosquaramide11bcatalyzed imine reduction of dihydro-β-carbolines (17a−f) and syntheses of (−)-coerulescine and (–)-horsfilineviaenantioselective oxidative rearrangement. Click to show full abstract

Keywords: reduction dihydro; synthesis; dihydro carbolines; oxidative rearrangement

Journal Title: RSC Advances
Year Published: 2020

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