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We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such… Click to show full abstract
We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such solids into physical mixtures of their constituents. Computational methods were employed in an attempt to identify possible reasons for these previously unrecognised effects of liquid additives on mechanochemical transformations.
Keywords:
liquid;
mechanochemical reactivity;
liquid additives;
reactivity inhibited;
prohibited reversed;
inhibited prohibited
Journal Title: Chemical Science
Year Published: 2021
Link to full text (if available)
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Journal Title: Chemical Science
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!