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Reversible polymorphic structural transition of crown-like nickel nanoclusters and its effect on conductivity.

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We report the reversible polymorphic phase transition of [Ni6(PET)12] (PET = phenylethanethiol) and its effect on the conductivity. This cluster's self-assembly leads to two polymorphic structures with distinct conductivity, caused… Click to show full abstract

We report the reversible polymorphic phase transition of [Ni6(PET)12] (PET = phenylethanethiol) and its effect on the conductivity. This cluster's self-assembly leads to two polymorphic structures with distinct conductivity, caused by variation of the non-covalent SS interactions. These results enlighten the effect of non-covalent interactions on conductivity.

Keywords: reversible polymorphic; transition; effect; conductivity; polymorphic structural; effect conductivity

Journal Title: Chemical communications
Year Published: 2021

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