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Easy wide scope access to luminescent fluorophosphoranes.

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The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by SNAr cyclization of (2'-F,2-(PR2)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to… Click to show full abstract

The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by SNAr cyclization of (2'-F,2-(PR2)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied and discussed.

Keywords: access luminescent; scope access; luminescent fluorophosphoranes; easy wide; wide scope

Journal Title: Chemical communications
Year Published: 2021

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