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A titanium(III) phosphite exhibits polymorph-distinct redox activity involving proton-coupled electron transfer.

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A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with… Click to show full abstract

A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle initiated with TiIII can produce H2 and transform organics.

Keywords: iii phosphite; electron transfer; proton; titanium iii; proton coupled; coupled electron

Journal Title: Chemical communications
Year Published: 2021

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