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Efficient NIR-I fluorescence photoswitching based on giant fluorescence quenching in photochromic nanoparticles.

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A photoswitchable near-infrared (NIR) fluorescent nanoparticle (NP) was designed and prepared. The NP showed a characteristic AIE property and high-contrast NIR fluorescence photoswitching with full reversibility. Such efficient NIR fluorescence… Click to show full abstract

A photoswitchable near-infrared (NIR) fluorescent nanoparticle (NP) was designed and prepared. The NP showed a characteristic AIE property and high-contrast NIR fluorescence photoswitching with full reversibility. Such efficient NIR fluorescence photoswitching originated from the amplified fluorescence quenching mechanism based on intermolecular energy transfer in a densely packed NP state.

Keywords: fluorescence quenching; fluorescence; fluorescence photoswitching; efficient nir; photoswitching based; nir fluorescence

Journal Title: Chemical communications
Year Published: 2021

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