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High nuclearity structurally - related Mn supertetrahedral T4 aggregates.

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The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4… Click to show full abstract

The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

Keywords: supertetrahedral aggregates; high nuclearity; chemistry; structurally related; related supertetrahedral; nuclearity structurally

Journal Title: Chemical communications
Year Published: 2021

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