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Mechanistic studies of reactive oxygen species mediated electrochemical radical reactions of alkyl iodides.

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Mechanistic studies of a reactive oxygen species mediated electrochemical radical reaction of alkyl iodides are described. Hydroxyl radicals and ozone are identified to be the active species involved in the… Click to show full abstract

Mechanistic studies of a reactive oxygen species mediated electrochemical radical reaction of alkyl iodides are described. Hydroxyl radicals and ozone are identified to be the active species involved in the formation of alkyl radicals under mildly reducing potential (-1.0 V vs. Ag QRE) in buffered acidic conditions (pH 3.6).

Keywords: reactive oxygen; mediated electrochemical; oxygen species; species mediated; mechanistic studies; studies reactive

Journal Title: Chemical communications
Year Published: 2021

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