Photo from wikipedia
Hydrazone compounds could be highly emissive in the solid state. However, most hydrazone-linking COFs are poorly luminescent. Here we report the enhancement of fluorescence in a 2D hydrazone-linking COF by… Click to show full abstract
Hydrazone compounds could be highly emissive in the solid state. However, most hydrazone-linking COFs are poorly luminescent. Here we report the enhancement of fluorescence in a 2D hydrazone-linking COF by side chain engineering. Stacking of the bulky and semi-rigid crown ether side chains restricts intramolecular rotation of the backbone around the hydrazone linkers, reducing the thermal dissipation and achieving 20-fold improved emission.
Keywords:
crown ether;
ether side;
side chains;
side;
enhanced emission
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!