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An inorganic-rich SEI induced by LiNO3 additive for a stable lithium metal anode in carbonate electrolyte.

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The dissolution of LiNO3 in carbonate electrolytes is achieved by introducing pyridine as a new carrier solvent owing to its higher Gutmann donor number than NO3-. The Li metal anode… Click to show full abstract

The dissolution of LiNO3 in carbonate electrolytes is achieved by introducing pyridine as a new carrier solvent owing to its higher Gutmann donor number than NO3-. The Li metal anode in LiNO3-containing carbonate electrolyte demonstrates a much enhanced reversibility due to the preferential reduction of LiNO3 and the formation of an inorganic-rich SEI.

Keywords: carbonate electrolyte; rich sei; inorganic rich; metal anode; carbonate

Journal Title: Chemical communications
Year Published: 2021

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