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Key to C2 production: selective C-C coupling for electrochemical CO2 reduction on copper alloy surfaces.

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The C-C coupling kinetic variations are observed on Cu alloys with Pt, Pd, or Au surface sites. The OC-COH coupling is kinetically more favorable than OC-CHO coupling, which originates from… Click to show full abstract

The C-C coupling kinetic variations are observed on Cu alloys with Pt, Pd, or Au surface sites. The OC-COH coupling is kinetically more favorable than OC-CHO coupling, which originates from increased reactivity of adsorbed *CO species. Linear energy relations for C-C association/dissociation could simplify the energetic evaluation for C2 production.

Keywords: production selective; production; coupling electrochemical; selective coupling; key production; electrochemical co2

Journal Title: Chemical communications
Year Published: 2021

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