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A heavy-metal-free desulfonylative Giese-type reaction of benzothiazole sulfones under visible-light conditions.

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A visible-light-induced desulfonylative Giese-type reaction has been developed. Essential to the success is the employment of Hantzsch ester to activate benzothiazole sulfones without any heavy-metal additives. Not only benzylic benzothiazole… Click to show full abstract

A visible-light-induced desulfonylative Giese-type reaction has been developed. Essential to the success is the employment of Hantzsch ester to activate benzothiazole sulfones without any heavy-metal additives. Not only benzylic benzothiazole sulfones but also alkyl ones were viable substrates and reacted with electron-deficient alkenes and a propiol amide.

Keywords: desulfonylative giese; giese type; visible light; heavy metal; type reaction; benzothiazole sulfones

Journal Title: Chemical communications
Year Published: 2021

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