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PET-RAFT single unit monomer insertion of β-methylstyrene derivatives: RAFT degradation and reaction selectivity.

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Reversible addition-fragmentation chain transfer (RAFT) single unit monomer insertion (SUMI) of β-methylstyrene derivatives into diverse RAFT agents presented fast reaction kinetics, but significant degradation of the SUMI products occurred due… Click to show full abstract

Reversible addition-fragmentation chain transfer (RAFT) single unit monomer insertion (SUMI) of β-methylstyrene derivatives into diverse RAFT agents presented fast reaction kinetics, but significant degradation of the SUMI products occurred due to a hydrogen abstraction reaction. Fortunately, such degradation can be suppressed through appropriate design of initial RAFT agents attributed to effective chain transfer and selective photoactivation.

Keywords: degradation; raft single; raft; single unit; reaction; unit monomer

Journal Title: Chemical communications
Year Published: 2021

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