Reactions of a silylene with a ketene and with carbon suboxide are reported, respectively leading to the first silaallene oxide and to a silylketene, whose reaction with water affords the… Click to show full abstract
Reactions of a silylene with a ketene and with carbon suboxide are reported, respectively leading to the first silaallene oxide and to a silylketene, whose reaction with water affords the first structurally characterised stable methyleneketene and constitutes a unique type of single-crystal-to-single-crystal transformation of a molecular solid by a stoichiometric gas-solid chemical reaction.
Keywords:
carbon;
carbon suboxide;
heterocyclic silylene;
silylene ferrocenediyl;
reactivity heterocyclic
Journal Title: Chemical communications
Year Published: 2021
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Journal Title: Chemical communications
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!