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Here we present the synthesis of a unique diferrous [2Fe-2S]0 complex with only three-coordinate iron ions via reduction of a four-coordinate diferric [2Fe-2S]2+ complex with concomitant ligand loss. The obtained… Click to show full abstract
Here we present the synthesis of a unique diferrous [2Fe-2S]0 complex with only three-coordinate iron ions via reduction of a four-coordinate diferric [2Fe-2S]2+ complex with concomitant ligand loss. The obtained compounds were thoroughly examined for their properties (e.g. by 57Fe Mössbauer spectroscopy and magnetic susceptibility measurements). Facile cleavage of the [2Fe-2S] rhombus, commonly seen as rather stable, by CS2 is also shown.
Keywords:
synthesis characterisation;
coordinate diferrous;
coordinate;
characterisation low;
low coordinate;
diferrous 2fe
Journal Title: Chemical communications
Year Published: 2021
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Journal Title: Chemical communications
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!