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A new noncentrosymmetric iron-iodate-fluoride Ba2[FeF4(IO3)2]IO3 was ingeniously obtained based on the centrosymmetric Ba[FeF4(IO3)] through chemical tailoring. Ba2[FeF4(IO3)2]IO3 exhibits a strong phase-matchable second-harmonic generation effect, a large band gap, and a… Click to show full abstract
A new noncentrosymmetric iron-iodate-fluoride Ba2[FeF4(IO3)2]IO3 was ingeniously obtained based on the centrosymmetric Ba[FeF4(IO3)] through chemical tailoring. Ba2[FeF4(IO3)2]IO3 exhibits a strong phase-matchable second-harmonic generation effect, a large band gap, and a wide mid-infrared transparent window. The chemical tailoring design based on oxide-fluoride anions affords a feasible approach to design nonlinear optical materials.
Keywords:
chemical tailoring;
io3;
fef4 io3;
ba2 fef4;
io3 io3
Journal Title: Chemical communications
Year Published: 2021
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!