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Accessing three oxidation states of cobalt in M6L3 nanoprisms with cobalt-porphyrin walls.

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Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3 nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated… Click to show full abstract

Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3 nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt-porphyrin nanocages have been characterized in CoI, CoII, and CoIII states.

Keywords: porphyrin walls; m6l3 nanoprisms; cobalt porphyrin; nanoprisms cobalt; three oxidation; accessing three

Journal Title: Chemical communications
Year Published: 2021

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