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Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids.

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We report herein an iridium-catalyzed asymmetric allylic esterification of racemic secondary allylic alcohols using free carboxylic acids as nucleophiles under mild conditions with broad functional group tolerance, exhibiting excellent regio-… Click to show full abstract

We report herein an iridium-catalyzed asymmetric allylic esterification of racemic secondary allylic alcohols using free carboxylic acids as nucleophiles under mild conditions with broad functional group tolerance, exhibiting excellent regio- and enantioselectivity .

Keywords: allylic esterification; carboxylic acids; iridium catalyzed; allylic alcohols; secondary allylic

Journal Title: Chemical communications
Year Published: 2021

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