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An autocatalytic organic reaction network based on cross-catalysis.

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Here we report a simple autocatalytic organic reaction network based on the redox chemistry of quinones and reactive oxygen species. Autocatalysis arises from the cross-activation between the H2O2-catalyzed deprotection of… Click to show full abstract

Here we report a simple autocatalytic organic reaction network based on the redox chemistry of quinones and reactive oxygen species. Autocatalysis arises from the cross-activation between the H2O2-catalyzed deprotection of a pro-benzoquinone arylboronic ester probe and the benzoquinone-catalyzed H2O2 production through redox cyling with ascorbate in an aerated buffered solution.

Keywords: network based; reaction network; organic reaction; autocatalytic organic

Journal Title: Chemical communications
Year Published: 2021

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