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Decorating an anisotropic Au13 core with dendron thiolates: enhancement of optical absorption and photoluminescence.

We successfully introduced up to 12 poly(benzyl ether)dendron-thiols of the second generation (D2SH) into the Au13 core of [Au23(ScC6H11)16]- while retaining the geometric structure. The decoration with D2SH enhanced the… Click to show full abstract

We successfully introduced up to 12 poly(benzyl ether)dendron-thiols of the second generation (D2SH) into the Au13 core of [Au23(ScC6H11)16]- while retaining the geometric structure. The decoration with D2SH enhanced the optical absorbance in the >2.5 eV region and the quantum yield of photoluminescence at ∼1.6 eV by ∼15 times.

Keywords: au13 core; photoluminescence; dendron; decorating anisotropic

Journal Title: Chemical communications
Year Published: 2021

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