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Triple-stranded triptycene-based metallo-supramolecular helicate displaying efficient encapsulation of bulky guest molecules.

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Triple-stranded metallo-supramolecular helicates were readily constructed by achieving a coordination of the gallium(iii) cation by ligands based on 2,7- and 2,6-disubstituted triptycenes. The significance of these building blocks in the… Click to show full abstract

Triple-stranded metallo-supramolecular helicates were readily constructed by achieving a coordination of the gallium(iii) cation by ligands based on 2,7- and 2,6-disubstituted triptycenes. The significance of these building blocks in the construction of helicates with the capability for guest encapsulation was also revealed.

Keywords: metallo supramolecular; based metallo; triptycene based; triple stranded; encapsulation; stranded triptycene

Journal Title: Chemical communications
Year Published: 2022

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