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Photochemical and electrochemical C-N borylation of arylhydrazines.

The C-N borylation of arylhydrazine hydrochlorides with bis(pinacolato)diboron was achieved under photochemical and electrochemical conditions, respectively. This novel and scalable transformation provides two efficient and mild transition-metal-free synthetic routes towards… Click to show full abstract

The C-N borylation of arylhydrazine hydrochlorides with bis(pinacolato)diboron was achieved under photochemical and electrochemical conditions, respectively. This novel and scalable transformation provides two efficient and mild transition-metal-free synthetic routes towards aryl boronate esters from easily available arylhydrazines.

Keywords: borylation; borylation arylhydrazines; photochemical electrochemical; electrochemical borylation

Journal Title: Chemical communications
Year Published: 2022

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