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In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes.

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Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall… Click to show full abstract

Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields.

Keywords: borane complexes; carbohalogenation; generation radical; situ generation; amine borane

Journal Title: Chemical communications
Year Published: 2022

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