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Fluorinated tris(pyrazolyl)borate supporting ligands enable the stabilization of silver(I) bonded to a neutral, organometallic Fe(CO)5 ligand. The Ag-Fe interaction in these molecules is mainly electrostatic in nature, but σ-donor and… Click to show full abstract
Fluorinated tris(pyrazolyl)borate supporting ligands enable the stabilization of silver(I) bonded to a neutral, organometallic Fe(CO)5 ligand. The Ag-Fe interaction in these molecules is mainly electrostatic in nature, but σ-donor and backbonding contributions between the two metal fragments also play notable roles, which can be modulated by the scorpionate substituents.
Keywords:
iron pentacarbonyl;
ligands silver;
pentacarbonyl ligands;
silver scorpionates
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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recommendations!