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A novel transfer-catalyst-free biomimetic reduction of the tetrasubstituted olefins 3-sulfonyl coumarins with the chiral and regenerable [2.2]paracyclophane-based NAD(P)H model CYNAM has been developed, affording chiral 3-sulfonyl dihydrocoumarins with excellent enantioselectivities. Click to show full abstract
A novel transfer-catalyst-free biomimetic reduction of the tetrasubstituted olefins 3-sulfonyl coumarins with the chiral and regenerable [2.2]paracyclophane-based NAD(P)H model CYNAM has been developed, affording chiral 3-sulfonyl dihydrocoumarins with excellent enantioselectivities.
Keywords:
free biomimetic;
catalyst free;
transfer catalyst;
sulfonyl coumarins;
nad model;
reduction
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!