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Guanidinium solvents with exceptional hydrogen bond donating abilities.

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Guanidinium chloride-based solvents have been prepared using deep eutectic solvent principles. Strong hydrogen-bond (H-bond) donating abilities are established based on a range of measures of solvent polarity, including a novel… Click to show full abstract

Guanidinium chloride-based solvents have been prepared using deep eutectic solvent principles. Strong hydrogen-bond (H-bond) donating abilities are established based on a range of measures of solvent polarity, including a novel 31P NMR chemical shift method. The physical properties and origin of the strong H-bonding ability of these solvents have been explored.

Keywords: donating abilities; hydrogen bond; bond donating; guanidinium; bond

Journal Title: Chemical communications
Year Published: 2022

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