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The reactions of bis(2-pyridylthio)methane with Me2Zn and Zn[N(SiMe3)2]2 afford [Bptm]ZnMe and [Bptm]ZnN(SiMe3)2, thereby providing access to a variety of other [Bptm]ZnX derivatives, including the zinc hydride complex [Bptm]ZnH, which serves… Click to show full abstract
The reactions of bis(2-pyridylthio)methane with Me2Zn and Zn[N(SiMe3)2]2 afford [Bptm]ZnMe and [Bptm]ZnN(SiMe3)2, thereby providing access to a variety of other [Bptm]ZnX derivatives, including the zinc hydride complex [Bptm]ZnH, which serves as a catalyst for the reduction of CO2 and other carbonyl compounds via hydrosilylation and hydroboration.
Keywords:
bis pyridylthio;
hydrosilylation hydroboration;
bptm;
zinc hydride;
co2
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!