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Late-stage modification of π-electron systems based on asymmetric oxidation of a medium-sized sulfur-containing ring.

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The asymmetric oxidation of a sulfur-containing nine-membered heterocycle was achieved for the late-stage introduction of chirality to the substituents of π-electron systems. The oxidation of the sulfur atom considerably influenced… Click to show full abstract

The asymmetric oxidation of a sulfur-containing nine-membered heterocycle was achieved for the late-stage introduction of chirality to the substituents of π-electron systems. The oxidation of the sulfur atom considerably influenced the phase-transition behaviour and crystallinity of the resulting π-electron systems.

Keywords: oxidation; electron systems; sulfur containing; late stage; asymmetric oxidation

Journal Title: Chemical communications
Year Published: 2022

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