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Bis(1-bora-4-phosphorinane) metal complexes have been synthesized using a Cp*M-protecting (M = FeIICl, CoI, Cp* = C5Me5-) strategy and structurally authenticated by NMR spectroscopy and single crystal X-ray diffraction. Synthesis of… Click to show full abstract
Bis(1-bora-4-phosphorinane) metal complexes have been synthesized using a Cp*M-protecting (M = FeIICl, CoI, Cp* = C5Me5-) strategy and structurally authenticated by NMR spectroscopy and single crystal X-ray diffraction. Synthesis of these scaffolds is highly sensitive to the identity of vinylphosphine precursor. This approach provides a new method for the generation of saturated P,B-containing main-group ring systems.
Keywords:
bis bora;
bora phosphorinane;
spectroscopy;
closure complexes;
ring closure;
phosphorinane ring
Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!