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Amorphous metal-organic frameworks obtained from a crystalline precursor for the capture of iodine with high capacities.

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Two amorphous metal-organic frameworks (aMOFs) were obtained from crystalline Co-MOF (SCNU-Z6) via temperature-induced (aT-SCNU-Z6) and water-immersed (aW-SCNU-Z6) approaches. They exhibited high iodine uptake, with the adsorption capacities of aT-SCNU-Z6 and… Click to show full abstract

Two amorphous metal-organic frameworks (aMOFs) were obtained from crystalline Co-MOF (SCNU-Z6) via temperature-induced (aT-SCNU-Z6) and water-immersed (aW-SCNU-Z6) approaches. They exhibited high iodine uptake, with the adsorption capacities of aT-SCNU-Z6 and aW-SCNU-Z6 reaching 2.05 and 5.04 g g-1, respectively. This work is the first report of iodine uptake by aMOFs.

Keywords: organic frameworks; amorphous metal; obtained crystalline; metal organic

Journal Title: Chemical communications
Year Published: 2022

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