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First example of solid-state luminescent borasiloxane-based chiral helices assembled through N-B bonds.

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The reaction between differently substituted borasiloxanes and 2,5-bis(3-pyridylethynyl)thiophene provided the first example of luminescent borasiloxane-based chiral helices held together by N-B bonds. The starting building blocks and the helices were… Click to show full abstract

The reaction between differently substituted borasiloxanes and 2,5-bis(3-pyridylethynyl)thiophene provided the first example of luminescent borasiloxane-based chiral helices held together by N-B bonds. The starting building blocks and the helices were fully characterized, and the nature of the N-B bond rationalized by means of theoretical calculations.

Keywords: based chiral; first example; chiral helices; luminescent borasiloxane; borasiloxane based

Journal Title: Dalton transactions
Year Published: 2021

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