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Trinuclear complex [Au2Ag(dppmaphen)2(CN)2]PF6 photoluminesces on exposure to low molecular weight alcohols. This emission is likely due to C-Hπ interactions between the analyte and -PPh2 group, that inhibits non-radiative relaxation of… Click to show full abstract
Trinuclear complex [Au2Ag(dppmaphen)2(CN)2]PF6 photoluminesces on exposure to low molecular weight alcohols. This emission is likely due to C-Hπ interactions between the analyte and -PPh2 group, that inhibits non-radiative relaxation of the photoexcited state. Photoluminescene was quenched by removing the analyte under a stream of N2 or replacing it with H2O. This on/off switching was clearly visible, relatively rapid and recyclable.
Keywords:
relatively rapid;
pnn coordination;
rapid reversible;
photoluminescent pnn;
coordination complex;
complex relatively
Journal Title: Dalton transactions
Year Published: 2021
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!