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A Gd-based borate-carbonate framework exhibiting a large magnetocaloric effect at a low magnetic field.

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A 3D borate-carbonate framework, GdB(OH)4CO3 (1), was synthesized. Magnetic study reveals that its MCE is up to 33.5 J kg-1 K-1 at 2 K and 2 T, due to the… Click to show full abstract

A 3D borate-carbonate framework, GdB(OH)4CO3 (1), was synthesized. Magnetic study reveals that its MCE is up to 33.5 J kg-1 K-1 at 2 K and 2 T, due to the introduction of a long magnetic exchange path of Gd-O-B-O-Gd leading to 1 exhibiting weak magnetic interaction.

Keywords: carbonate framework; based borate; framework exhibiting; borate carbonate

Journal Title: Dalton transactions
Year Published: 2021

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