Alkylene-bridged bis-N-heterocyclic carbene ligands working as strong σ-donors enhance the reactivity of the Pt3S2 core in a triplatinum complex. Although an Ag(I) ion possibly reacts with the Pt-Pt bond, one… Click to show full abstract
Alkylene-bridged bis-N-heterocyclic carbene ligands working as strong σ-donors enhance the reactivity of the Pt3S2 core in a triplatinum complex. Although an Ag(I) ion possibly reacts with the Pt-Pt bond, one of the sulfide ligands coordinates to an Ag(I) ion due to the steric hindrance of the ligands.
               
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