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The synthesis of alkenylated-o-carboranes via photoalkenylation of iodocarboranes with unactivated alkenes has been achieved. This strategy features a transition metal-free protocol, a light-promoted reaction under mild reaction conditions, broad substrate… Click to show full abstract
The synthesis of alkenylated-o-carboranes via photoalkenylation of iodocarboranes with unactivated alkenes has been achieved. This strategy features a transition metal-free protocol, a light-promoted reaction under mild reaction conditions, broad substrate scope and good functional group tolerance. Control experiments suggest that the reaction may involve the cage C-centered radical species.
Keywords:
light enabled;
reaction;
enabled alkenylation;
unactivated alkenes;
iodocarboranes unactivated;
alkenylation iodocarboranes
Journal Title: Dalton transactions
Year Published: 2021
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!