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The zinc hydride compound, [Tptm]ZnH, may achieve the reduction of CO2 by (RO)3SiH (R = Me, Et) to the methanol oxidation level, (MeO)xSi(OR)4-x, via the formate species, HCO2Si(OR)3. However, because… Click to show full abstract
The zinc hydride compound, [Tptm]ZnH, may achieve the reduction of CO2 by (RO)3SiH (R = Me, Et) to the methanol oxidation level, (MeO)xSi(OR)4-x, via the formate species, HCO2Si(OR)3. However, because insertion of CO2 into the Zn-H bond is more facile than insertion of HCO2Si(OR)3, conversion of HCO2Si(OR)3 to the methanol level only occurs to a significant extent in the absence of CO2.
Keywords:
hydride compound;
methanol level;
compound tptm;
level;
zinc hydride;
tptm znh
Journal Title: Dalton transactions
Year Published: 2022
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Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
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recommendations!