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Unveiling the new function of uranyl molecular clusters as fluorometric sensors for UV and X-ray dosimetry.

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Simple synthetic modulation based on uranyl acetate and phenanthroline has resulted in two uranyl clusters (1 and 2) with different topologies and nuclearities. Notably, the dimeric complex exhibits distinct luminescence… Click to show full abstract

Simple synthetic modulation based on uranyl acetate and phenanthroline has resulted in two uranyl clusters (1 and 2) with different topologies and nuclearities. Notably, the dimeric complex exhibits distinct luminescence quenching upon UV and X-ray irradiation with detection limits of 4.30 × 10-6 J and 0.32 Gy, respectively. To advance the practical application, 1 was further fabricated with polyvinylidene fluoride into a flexible strip as a UV and X-ray indicator.

Keywords: clusters fluorometric; molecular clusters; function uranyl; new function; uranyl molecular; unveiling new

Journal Title: Dalton transactions
Year Published: 2022

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