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Optimization of irradiation parameters for 40Ar/39Ar dating by Argus VI multi-collector mass spectrometry

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In 40Ar/39Ar dating, 39ArK generated is dependent on irradiation conditions, and the accumulation fast neutron fluence is a critical parameter for 40Ar/39Ar dating. With technological advancement, especially in the ultra-low… Click to show full abstract

In 40Ar/39Ar dating, 39ArK generated is dependent on irradiation conditions, and the accumulation fast neutron fluence is a critical parameter for 40Ar/39Ar dating. With technological advancement, especially in the ultra-low background and multicollector technology, the boundary conditions to choose irradiation conditions have been greatly improved. Based on the detected and processed signal, the maximum boundary condition of 40Ar*/39Ar can be up to 5750, meaning that very low 39Ar signals can yield considerable analytical accuracy. In this study, one biotite sample (ZBH-25) was irradiated for 4 hours to assess the modified irradiation conditions, and the high 40Ar*/39Ar ratio up to 4100 could yield ∼1% analytical uncertainty. This reveals that the new boundary condition is useful to choose fast neutron fluence, especially for very old or low K/Ca ratio samples.

Keywords: 39ar dating; irradiation conditions; spectrometry optimization; 40ar 39ar; irradiation

Journal Title: Journal of Analytical Atomic Spectrometry
Year Published: 2021

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