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Group VIII coordination complexes of bidentate P^N ligands bearing π-extended quinoline or phenanthridine N-heterocycles

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Group 8 complexes of π-extended N-heterocyclic ligands present some unexpected results. Benzannulation shifts the lowest energy excitation to the blue by impacting the character of the transition rather than affecting… Click to show full abstract

Group 8 complexes of π-extended N-heterocyclic ligands present some unexpected results. Benzannulation shifts the lowest energy excitation to the blue by impacting the character of the transition rather than affecting frontier orbital energies.

Keywords: group viii; coordination complexes; complexes bidentate; viii coordination; bidentate ligands; group

Journal Title: New Journal of Chemistry
Year Published: 2021

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