Group 8 complexes of π-extended N-heterocyclic ligands present some unexpected results. Benzannulation shifts the lowest energy excitation to the blue by impacting the character of the transition rather than affecting… Click to show full abstract
Group 8 complexes of π-extended N-heterocyclic ligands present some unexpected results. Benzannulation shifts the lowest energy excitation to the blue by impacting the character of the transition rather than affecting frontier orbital energies.
               
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